Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites     

Milton BLANDER  Arthur D. PELTON  In‐Ho JUNG  Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.  相似文献   

Composition and temperatures of the topside ionosphere over Arecibo     

M.C. Ho  D.R. Moorcroft 《Planetary and Space Science》1975,23(2):315-322

Results of analysis of about 150 autocorrelation functions are presented for the period from about 2300 hr on 5 October to about 1200 hr on 7 October 1967. A large percentage concentration of helium ions are observed. It reaches a value as high as 50 per cent with a maximum at around 800 km. Downward heat fluxes deduced from the temperature variations yield a value of about 2–2.5 × 10⁹ eV cm^?2 sec^?1 during the period 1200–1600 hr and a value of about 1.5 × 10⁸ eV cm^?2 sec^?1 during the period 0100–0400 hr at night. These agree well with other measurements. The O⁺ ions are found not to be in diffusive equilibrium, and from the O⁺ fluxes and the electron density profiles, the O⁺ drift velocity has been estimated. It is found that the speed can be as high as 1–5 × 10³ cm sec^?1 even at altitudes as high as 700 km.  相似文献   

Statistical control chart for regime identification in volcanic time series     

Chih-Hsiang Ho 《Mathematical Geology》1992,24(7):775-787

In an important paper, Mulargia et al. (1987) address the importance of quantitative and objective identification of different regimes of a volcano. They develop a procedure based on the two-sample Kolmogorov-Smirnov (K-S) statistic. The K-S test is a general-purpose test that discriminates between two data sets as belonging to two different regimes based on their empirical distribution functions. The empirical distribution function is designed to describe the aggregate behavior of the volcanic activity, and it is constructed from the orders of the length of the collected repose times in each data set. In this article, we use the idea of statistical process control to distinguish between the variation inherent in the observed repose times and the extraordinary variation that signals a real change in the regimes. We construct a table of control limits, and we demonstrate the procedure of regime identification based on a simple control chart. It shows a point outside the control limits almost as soon as the process enters a new regime. The basis of the statistical process control mechanism is a simple Poisson process, which is state of the art. The proposed control charting procedure is an eruption by eruption procedure, which follows the original chronological order of the eruptions. This procedure is applied to the eruptive history of the Mount Etna volcano. The application shows schematically that the procedure presents a visual interpretation of the identified regimes and can be practically translated for tabular or manual use.  相似文献   

Major human Hepatitis A virus genotype in Hong Kong marine waters and detection by real-time PCR     

Yang N  Chu DL  Wong MM  Qi H  Wu RS  Kong RY 《Marine pollution bulletin》2011,62(12):2654-2658

Marine waters from seven sites around Hong Kong with varying levels of sewage pollution were analyzed for Hepatitis A virus (HAV) by PCR cloning and DNA sequencing of the highly variable VP1/2A junction of the HAV genome. Phylogenetic analysis of 10 PCR clones from each of the HAV-positive marine sites indicated that human HAV genotype IB is the most widely distributed type in Hong Kong waters. A sensitive and quantitative TaqMan-based PCR method targeting the 5′-noncoding region (5′-NCR) of HAV was used to quantify HAV particles in marine water samples along with the total Escherichiacoli counts being enumerated on TBX medium for comparison. Our results showed that no correlation of any significance between HAV and E. coli counts was observed which underscores the inadequacy in using E. coli as a sanitary standard to predict the levels of HAV in marine waters.  相似文献   

Outlying plasmasphere structure detected by whistlers     

D. Ho  D.L. Carpenter 《Planetary and Space Science》1976,24(10):987-994

Whistlers recorded at Eights ($\text{L ? 4}$) and Byrd ($\text{f ? 7}$), Antarctica have been used to study large-scale structure in equatorial plasma density at geocentric distances $\text{?3–6}\text{R}{}_{\mathrm{E}}$. The observations were made during conditions of magnetic quieting following moderate disturbance. The structures were detected by a “scanning” process involving relative motion, at about one tenth of the Earth's angular velocity or greater, between the observed density features and the observing whistler station or stations. Three case studies are described, from 26 March 1965, 11 May 1965 and 29 August 1966. The cases support satellite results by showing outlying high density regions at $\text{?4–6}\text{R}{}_{\mathrm{E}}$ that are separated from the main plasmasphere by trough-like depressions ranging in width from $\text{?0.2}$ to 1 R_E. The structures evidently endured for periods of 12 hr or more. In the cases of deepest quieting their slow east-west motions with respect to the Earth are probably of dynamo origin. The cases observed during deep quieting (11 May 1965 and 29 August 1966) suggest the approximate rotation with the Earth of structure formed during previous moderate disturbance activity in the dusk sector. The third case, from 26 March 1965, may represent a structure formed near local midnight. The reported structures appear to be closely related to the bulge phenomenon. The present work supports other experimental and theoretical evidence that the dusk sector is one of major importance in the generation of outlying density structure. It is inferred that irregularities of the type reported here regularly develop near 4–5 R_E during moderate substorm activity. This research suggests that at least a major class of the density structures that develop near 4 R_E are tail-like in nature, joined to the main body of the plasmasphere. The apparent disagreement with Chappell's results from OGO 5, which are interpreted as showing regions of “detached” plasma beyond 5 R_E, may be related to the pronounced spatial structure of electric fields observed in high-latitude ionospheric regions that are conjugate to the magnetospheric regions in which the OGO-5 observations were made.  相似文献   

Venus I. Carbon monoxide distribution and molecular-line searches     

W.J. Wilson  M.J. Klein  R.K. Kahar  S. Gulkis  E.T. Olsen  P.T.P. Ho 《Icarus》1981,45(3):624-637

An observational program to study variations of the vertical distribution of CO in the Venus atmosphere is presented. Measurements of the J = 0 → 1 absorption line at 2.6 mm wavelength are reported for two phase angles in 1977, one near eastern elongation (Feb.) and the other near inferior conjunction (Apr.). The two spectra are significantly different, with the April absorption line being narrower and deeper. The results of numerical inversion calculations show that the CO mixing ratio increases a factor of ～ 100 between 78 and 100 km and that the CO abundance above ～ 100 km is greatest on the night-side hemisphere. These conclusions are in qualitative agreement with theoretical models. In addition to the CO observations, a search for other molecules was made to provide further information on the composition of the Venus middle atmosphere. The J = 0 → 1 transition of ¹³CO was detected and upper limits were derived for nine other molecules.  相似文献   

Characteristics of tephra in Holocene lake sediments on King George Island, West Antarctica: implications for deglaciation and paleoenvironment     

Yong Il Lee  Hyoun Soo Lim  Ho Il Yoon  Andrzej Tatur 《Quaternary Science Reviews》2007,26(25-28):3167-3178

Several reworked tephra layers in gravity-flow deposits are present in lacustrine core sediments collected from Hotel and Rudy Lakes on King George Island, South Shetland Islands, maritime sub-Antarctica. This study tests the values of tephra for establishing regional tephrochronologies for lakes in ice-covered landscapes in the vicinity of volcanoes. The tephra record is more abundant in a long Hotel Lake core (515 cm long). This study uses volcanic glass samples from five tephra layers of Hotel Lake and from one tephra layer of Rudy Lake. Morphologically, tephras are mixtures of basaltic and pumice shards, both having various degrees of vesicularity. Major element analyses of glass shards reveal that the majority of the glass fragments belong to basic glass (<60 wt% SiO₂), compositionally ranging from basalt to low-silica andesite and subalkaline series medium-K tholeiites, probably sourced from Deception Island located 130 km southwest of King George Island. Less than 20% of tephra belongs to silicic glass and occurs in three tephra horizons E of Hotel Lake. However, source volcano(es) for about 10% of basic tephra and silicic tephra are not readily identified from nearby volcanic centers. Except for the studied tephra in Rudy Lake, all tephra samples in Hotel Lake are not ashfall deposits but reworked and redeposited pyroclasts derived from retreating ice sheet, resulting in the occurrence of geochemically equivalent tephra samples in different tephra horizons. The dating of the studied tephra horizons represents the timing of deglaciation rather than that of volcanic eruptions. The result of this study implies that combined with sedimentological information more chemical criterion is necessary to study tephrochronology and regional correlation and to understand paleoenvironmental changes using tephra.  相似文献   

Freeze thaw cycles in Toronto, Canada in a changing climate     

E. Ho  W. A. Gough 《Theoretical and Applied Climatology》2006,83(1-4):203-210

Summary Freeze thaw cycles are examined in Toronto Canada. Using data from 1960 to 1989 for three Toronto area weather stations, trends in freeze thaw activity, the relationship to mean monthly temperature and projections of freeze thaw activity are examined. For downtown Toronto the annual frequency of freeze thaw cycles is decreasing significantly, most notably in the shoulder months of October and April. At the Pearson International Airport and the Toronto Island Airport similar annual trends were not found, however there was evidence of decreased freeze thaw activity in April and October. Polynomial curve fitting provided functional relationships between mean monthly temperature and freeze thaw activity. These relationships enabled the assessment of freeze thaw activity under synthetic warming conditions. The results of this analysis show that the warming of the magnitude typically projected for the rest of this century will not likely generate a significant change in the freeze thaw activity although there are indications that the freeze thaw season will contract.  相似文献   

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst   总被引：5，自引：0，他引：5  

Kyung Ho Park  B. Ramachandra Reddy  D. Mohapatra  Chul-Woo Nam 《International Journal of Mineral Processing》2006,80(2-4):261-265

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.  相似文献   

Classifying coastal waters: Current necessity and historical perspective     

J. C. Kurtz  N. D. Detenbeck  V. D. Engle  K. Ho  L. M. Smith  S. J. Jordan  D. Campbell 《Estuaries and Coasts》2006,29(1):107-123

Coastal ecosystems are ecologically and commercially valuable, productive habitats that are experiencing escalating compromises of their structural and functional integrity. The Clean Water Act (USC 1972) requires identification of impaired water bodies and determination of the causes of impairment. Classification simplifies these determinations, because estuaries within a class are more likely to respond similarly to particular stressors. We reviewed existing classification systems for their applicability to grouping coastal marine and Great Lakes water bodies based on their responses to aquatic stressors, including nutrients, toxic substances, suspended sediments, habitat alteration, and combinations of stressors. Classification research historically addressed terrestrial and freshwater habitats rather than coastal habitats. Few efforts focused on stressor response, although many well-researched classification frameworks provide information pertinent to stressor response. Early coastal classifications relied on physical and hydrological properties, including geomorphology, general circulation patterns, and salinity. More recent classifications sort ecosystems into a few broad types and may integrate physical and biological factors. Among current efforts are those designed for conservation of sensitive habitats based on ecological processes that support patterns of biological diversity. Physical factors, including freshwater inflow, residence time, and flushing rates, affect sensitivity to stressors. Biological factors, such as primary production, grazing rates, and mineral cycling, also need to be considered in classification. We evaluate each existing classification system with respect to objectives, defining factors, extent of spatial and temporal applicability, existing sources of data, and relevance to aquatic stressors. We also consider classification methods in a generic sense and discuss their strengths and weaknesses for our purposes. Although few existing classifications are based on responses to stressors, may well-researched paradigms provide important information for improving our capabilities for classification, as an investigative and predictive management tool.  相似文献